Open AccessVelocity‐resolved Laser‐induced Desorption for Kinetics on Surface Adsorbates
Author(s) -
Pappendorf Kim,
Golibrzuch Kai,
Zhong TianLi,
Schwabe Sven,
Kitsopoulos Theofanis,
Wodtke Alec M.
Publication year - 2022
Publication title -
chemistry ‐ methods
Language(s) - English
Resource type - Journals
ISSN - 2628-9725
DOI - 10.1002/cmtd.202200028
Subject(s) - desorption , adsorption , laser , molecule , platinum , chemistry , analytical chemistry (journal) , atomic physics , metal , ammonia , kinetics , electron , materials science , optics , physics , organic chemistry , catalysis , nuclear physics , quantum mechanics
Invited for this month's cover are the groups of Alec M. Wodtke at the Georg‐August University in Göttigen (Germany) and at the University of Crete (Greece). The cover picture shows ammonia (NH 3 ) molecules adsorbed on an atomically flat platinum surface. An ultra‐short laser pulse hits the surface and heats up the metal electron rapidly to several thousand Kelvin within a few 100 fs. This high electronic temperature causes a fraction of the ammonia molecules to desorb with hyperthermal velocity from the surface. Depended on the laser intensity, the number of desorbing molecules is proportional to the surface coverage. Read the full text of their Research Article at 10.1002/cmtd.202200017.