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Adsorption of Brilliant Green from Aqueous Solutions onto Crosslinked Chitosan Graft Copolymers
Author(s) -
Özkahraman Bengi,
Bal Ayça,
Acar Işıl,
Güçlü Gamze
Publication year - 2011
Publication title -
clean – soil, air, water
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.444
H-Index - 66
eISSN - 1863-0669
pISSN - 1863-0650
DOI - 10.1002/clen.201000337
Subject(s) - chitosan , ammonium persulfate , adsorption , grafting , copolymer , aqueous solution , freundlich equation , langmuir , polymer chemistry , brilliant green , chemistry , nuclear chemistry , materials science , chemical engineering , polymerization , organic chemistry , polymer , engineering
In this study, graft copolymerization of itaconic acid (IA) and crotonic acid (CA) onto the crosslinked chitosan beads were carried out using ammonium persulfate as initiator. Grafted chitosan beads were characterized by FT‐IR analysis and grafting percentage determination. Grafting efficiency and add‐on percentages values of grafted chitosan beads were determined as 23–29 and 32–47%, respectively. Then, equilibrium isotherms and kinetics of brilliant green adsorption onto grafted chitosan beads were investigated. The results indicated that the pseudo‐second‐order kinetic model fitted better than the data obtained from pseudo‐first‐order model for the adsorption of brilliant green onto grafted chitosan beads. The fit of data for brilliant green (BG) adsorption onto grafted chitosan beads suggested that the Langmuir model gave closer fittings than the Freundlich model.