Ruthenium Olefin Metathesis Catalysts for the Ethenolysis of Renewable Feedstocks | Zendy

Schrodi Yann | Zendy; Ung Thay | Zendy; Vargas Angel | Zendy; Mkrtumyan Garik | Zendy; Lee Choon Woo | Zendy; Champagne Timothy M. | Zendy; Pederson Richard L. | Zendy; Hong Soon Hyeok | Zendy

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Ruthenium Olefin Metathesis Catalysts for the Ethenolysis of Renewable Feedstocks

Author(s) -

Schrodi Yann,

Ung Thay,

Vargas Angel,

Mkrtumyan Garik,

Lee Choon Woo,

Champagne Timothy M.,

Pederson Richard L.,

Hong Soon Hyeok

Publication year - 2008

Publication title -

clean – soil, air, water

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.444

H-Index - 66

eISSN - 1863-0669

pISSN - 1863-0650

DOI - 10.1002/clen.200800088

Subject(s) - ruthenium , catalysis , olefin metathesis , metathesis , carbene , olefin fiber , organic chemistry , chemistry , derivative (finance) , selectivity , acyclic diene metathesis , ring opening metathesis polymerisation , business , polymer , polymerization , finance

Ruthenium olefin metathesis catalysts have been evaluated for the ethenolysis of methyl oleate, a natural seed oil derivative, to produce useful terminal olefins. Several N ‐heterocyclic carbene‐based ruthenium catalysts demonstrate good activity and selectivity for the formation of terminal olefins. In particular, catalysts ( 10 ) and ( 21 ) achieved higher TONs (>20 000).

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