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A Top‐Down Approach towards Cu(I) Alkynyl Clusters with Unusual Geometry
Author(s) -
Li Huan,
Li Ting,
Liu Shuimiao,
Qu Mei,
Liang Linfeng,
Zhang Fengwei,
Zhang XianMing
Publication year - 2021
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.202000613
Subject(s) - chemistry , phosphine , cluster (spacecraft) , yield (engineering) , nanoparticle , photoluminescence , metal , copper , quantum yield , catalysis , crystallography , nanotechnology , combinatorial chemistry , organic chemistry , metallurgy , optoelectronics , materials science , physics , computer science , quantum mechanics , fluorescence , programming language
Main observation and conclusion To search for novel Cu(I) complexes, traditional approaches focus on designing and screening ligands, metal precursors and reaction parameters. In this report, we propose a top‐down approach, in which Cu precursor is first reduced to nanoparticles in the presence of alkynyl and phosphine ligands. The nanoparticles then undergo an auto‐oxidation step in open air to give CuO powder. During this process, a new tetranuclear Cu(I) cluster with an unprecedented centered triangular configuration, [Cu 4 (PhC≡C) 3 (dppp) 3 ]NO 3 , is isolated in the supernatant. To demonstrate the feasibility of such strategy, it is applied to synthesize another two new Cu(I) clusters, [Cu 6 (PhC≡C) 5 (dppe) 3 ]NO 3 and Cu 4 (PhC≡C) 4 (dpph) 2 . The latter has shown a photoluminescence at 511 nm with a quantum yield of as high as 69.84%.