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Phosphorus Ligands from the Zhang Lab: Design, Asymmetric Hydrogenation, and Industrial Applications
Author(s) -
Wan Feng,
Tang Wenjun
Publication year - 2021
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.202000605
Subject(s) - chemistry , phosphine , phosphorus , asymmetric hydrogenation , ligand (biochemistry) , combinatorial chemistry , catalysis , zhàng , enantioselective synthesis , organic chemistry , biochemistry , receptor , political science , law , china
Chiral phosphorus ligands have played a crucial role for the recent advances in asymmetric catalysis. This review summarizes chiral phosphorus ligands developed from the Laboratory of Professor Xumu Zhang in the latest 25 years. A number of iconic phosphorus ligands including bisphosphorus ligands with rigid chiral backbone such as BICP, PennPhos, TunePhos, and f ‐Binaphane, P ‐chiral bisphosphorus ligands TangPhos, Binapine, and DuanPhos, phosphine‐phosphoramidte ligand YanPhos, noncovalent interaction‐assisted ferrocenyl phosphorus ligand ZhaoPhos and WudaPhos, and tridentate ferrocenyl phosphorus ligands f ‐amphox are introduced, and their applications in asymmetric hydrogenation are emphasized.