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Recent Advances of Trifluoromethoxylation Reactions Using TFMS and TFBO
Author(s) -
Jiang Xiaohuan,
Tang Pingping
Publication year - 2021
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.202000465
Subject(s) - chemistry , trifluoromethyl , diligence , organic chemistry , psychology , social psychology , alkyl
Trifluoromethoxy (OCF 3 ) group has received increasing attention due to its strong electron‐withdrawing effect and high lipophilicity. However, methods for the synthesis of trifluoromethyl ethers are limited due to the reversible decomposition of trifluoromethoxide anion and limited trifluoromethoxylation reagents. This account mainly focuses on the recent advances of trifluoromethoxylation reactions with our new trifluoromethoxylation reagents.