Premium
Asymmetric Reactions Catalyzed by Chiral Tertiary Phosphines
Author(s) -
Wei Yin,
Shi Min
Publication year - 2020
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.202000160
Subject(s) - chemistry , cycloaddition , catalysis , domino , nucleophile , combinatorial chemistry , lewis acids and bases , enantioselective synthesis , reaction conditions , organic chemistry
Chiral tertiary phosphines are versatile Lewis base catalysts capable of promoting a wide range of asymmetric reactions. In particular, the recent designed chiral phosphines based on the concept of bi‐/multifunctionality have been demonstrated to be effective catalysts for many types of asymmetric reactions such as (aza)‐MBH reaction/RC reaction, cycloaddition reaction, domino reaction, nucleophilic addition reaction, etc . This review summarizes the recent advances in this field and highlights the selected significant achievements.