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Visible Light Driven Copper(I) Catalyzed Oxyamination of Electron Deficient Alkenes †
Author(s) -
Li Sanliang,
Chen Qiaoyu,
Li Wenbo,
Gu Guangxin,
Zhang Junliang
Publication year - 2020
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.202000105
Subject(s) - chemistry , regioselectivity , catalysis , intermolecular force , amine gas treating , copper , substrate (aquarium) , photochemistry , visible spectrum , electron , oxygen , organic chemistry , molecule , oceanography , physics , optoelectronics , quantum mechanics , geology
Summary of main observation and conclusion A visible light driven Cu(I)‐catalyzed intermolecular oxyamination of electron‐deficient olefins has been achieved by using O ‐benzoylhydroxylamines as donors both for amine and oxygen. The transformation properties afford mild conditions and a wide substrate scope, providing access to ester derivatives of β ‐amino alcohols with good yields and high regioselectivity.