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Zinc Powder Catalysed Formylation and Urealation of Amines Using CO 2 as a C1 Building Block †
Author(s) -
Du Chongyang,
Chen Yaofeng
Publication year - 2020
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.202000072
Subject(s) - formylation , chemistry , zinc , catalysis , organic chemistry , formamides , formamide , combinatorial chemistry
Zn powder (2 mol%) is able to catalyse formylation and urealation of amines with CO 2 and (EtO) 3 SiH: reactions of secondary amines give formamides, while those of primary aromatic amines provide urea derivatives.