Zig‐Zag Diphosphene Oligomers Linked by Silver(I) Cation | Zendy

Pan Xiaobo | Zendy; Zhang Li | Zendy; Zhao Yue | Zendy; Tan Gengwen | Zendy; Ruan Huapeng | Zendy; Wang Xinping | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Zig‐Zag Diphosphene Oligomers Linked by Silver(I) Cation

Author(s) -

Pan Xiaobo,

Zhang Li,

Zhao Yue,

Tan Gengwen,

Ruan Huapeng,

Wang Xinping

Publication year - 2020

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.201900385

Subject(s) - chemistry , cationic polymerization , molecule , crystallography , atom (system on chip) , stereochemistry , tetrahedron , polymer chemistry , organic chemistry , computer science , embedded system

Summary of main observation and conclusion The coordination of silver cation to diphosphene Mes*P=PMes* ( 1 , Mes* = t Bu 3 C 6 H 2 ) was investigated in detail. The reaction of 1 with Ag[Al(OR F ) 4 ] (OR F = OC(CF 3 ) 3 ) in the ratios of 2 : 1, 3 : 2 and 1 : 2 led to the formation of the first cationic silver linked diphosphene complexes 2 — 4 . Complexes 2 and 3 contain two and three diphosphene molecules linked by the linear Ag(I) cation, respectively, and they feature unusual zig‐zag topologies. Complex 4 is a dinuclear silver complex, and each Ag(I) center features a tetrahedral geometry, coordinated by one phosphorus atom of diphosphene 1 and three chloro atoms of two CH 2 Cl 2 molecules.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research