Rhenium‐Catalyzed Decarboxylative Tri‐/Difluoromethylation of Styrenes with Fluorinated Carboxylic Acid‐Derived Hypervalent Iodine Reagents | Zendy

Wang Yin | Zendy; Yang Yunhui | Zendy; Wang Congyang | Zendy

Premium

Rhenium‐Catalyzed Decarboxylative Tri‐/Difluoromethylation of Styrenes with Fluorinated Carboxylic Acid‐Derived Hypervalent Iodine Reagents

Author(s) -

Wang Yin,

Yang Yunhui,

Wang Congyang

Publication year - 2019

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.201900296

Subject(s) - hypervalent molecule , chemistry , trifluoromethylation , reagent , rhenium , iodine , catalysis , organic chemistry , combinatorial chemistry , alkyl , trifluoromethyl

Summary of main observation and conclusion Herein, unprecedented rhenium‐catalyzed decarboxylative oxytri‐/difluoromethylation and Heck‐type trifluoromethylation of styrenes have been developed by using hypervalent iodine(III) reagents derived from cheap, stable, and easy‐handling fluorinated carboxylic acids. Mechanistic studies revealed a radical decarboxylative trifluoromethylation pathway occurring in these reactions.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research