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Synergistically Directed Assembly of Aromatic Stacks Based Metal‐Organic Frameworks by Donor‐Acceptor and Coordination Interactions
Author(s) -
Wang Xi,
Zhang Ying,
Chang Ze,
Huang Hui,
Liu XiaoTing,
Xu Jialiang,
Bu XianHe
Publication year - 2019
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201900247
Subject(s) - coronene , chemistry , sbus , metal organic framework , acceptor , coordination complex , combinatorial chemistry , metal , molecule , organic chemistry , physics , adsorption , condensed matter physics
Summary of main observation and conclusion A synergistically directed assembly approach to distinctive metal‐organic frameworks utilizing both donor‐acceptor (D‐A) interaction from aromatic systems and coordination interactions is presented. Based on such an approach, the coronene‐tpt (tpt = 2,4,6‐tri(4‐pyridyl)‐1,3,5‐triazine) stacks based coronene‐MOF‐1 — 4 have been successfully fabricated. Their structural discrepancies with coronene‐ absent control products, 1′ — 4′ , illustrate clearly the significance of coronene‐tpt based D‐A interactions in these architectures. All these coronene‐MOFs contain varied coronene‐tpt stacks as organic secondary building blocks (SBUs), which are closely interrelated with the coordination based framework structures. Moreover, porous coronene‐MOF‐1 and ‐2 exhibit high physicochemical stability and significant light hydrocarbons storage and separation performances.