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Transition Metal–Catalyzed Allylic C(sp 3 )–H Functionalization via η 3 ‐Allylmetal Intermediate
Author(s) -
Wang Ronghua,
Luan Yuxin,
Ye Mengchun
Publication year - 2019
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201900140
Subject(s) - allylic rearrangement , chemistry , catalysis , transition metal , surface modification , metal , combinatorial chemistry , medicinal chemistry , organic chemistry
As an efficient and facile access to linear or branched allylic compounds, transition metal‐catalyzed allylic C(sp 3 )–H functionalization reaction via η 3 ‐allylmetal intermediates has gained increasing interest in recent years. Pd, Rh, Ru, Ir, Fe and Co‐catalyzed systems have all been successfully achieved, affording various allylic compounds bearing a diverse set of functionalities. Herein, we provide a comprehensive review of this burgeoning field according to different transition metal catalysts .