Transition Metal–Catalyzed Allylic C(sp 3 )–H Functionalization  via η  3 ‐Allylmetal Intermediate | Zendy

Wang Ronghua | Zendy; Luan Yuxin | Zendy; Ye Mengchun | Zendy

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Transition Metal–Catalyzed Allylic C(sp 3 )–H Functionalization via η 3 ‐Allylmetal Intermediate

Author(s) -

Wang Ronghua,

Luan Yuxin,

Ye Mengchun

Publication year - 2019

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.201900140

Subject(s) - allylic rearrangement , chemistry , catalysis , transition metal , surface modification , metal , combinatorial chemistry , medicinal chemistry , organic chemistry

As an efficient and facile access to linear or branched allylic compounds, transition metal‐catalyzed allylic C(sp 3 )–H functionalization reaction via η 3 ‐allylmetal intermediates has gained increasing interest in recent years. Pd, Rh, Ru, Ir, Fe and Co‐catalyzed systems have all been successfully achieved, affording various allylic compounds bearing a diverse set of functionalities. Herein, we provide a comprehensive review of this burgeoning field according to different transition metal catalysts .

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