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Heterocyclic Carbene‐Catalyzed Hydride Transfer in the Hydroboration of Carbonyl Compounds
Author(s) -
Li Tianhao,
Zhang Jianying,
Cui Chunming
Publication year - 2019
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201900139
Subject(s) - hydroboration , chemistry , carbene , hydride , catalysis , organic chemistry , combinatorial chemistry , photochemistry , hydrogen
Summary of main observation and conclusion N ‐Heterocyclic carbene (NHC) enabled the highly efficient catalytic hydroboration of a wide range of ketones and aldehydes under mild conditions, and a new mechanism of catalytic hydroboration reaction which involves direct hydride transfer is proposed.