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Cover Picture: Palladium‐Catalyzed Intermolecular Oxidative Coupling Reactions of ( Z )‐Enamines with Isocyanides through Selective β‐C(sp 2 )‐H and/or C=C Bond Cleavage (Chin. J. Chem. 8/2018)
Author(s) -
Hu Weigao,
Zheng Jia,
Li Meng,
Wu Wanqing,
Liu Haiyang,
Jiang Huanfeng
Publication year - 2018
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201880081
Subject(s) - chemistry , intermolecular force , intramolecular force , palladium , catalysis , bond cleavage , hydrogen bond , medicinal chemistry , oxidative coupling of methane , oxidative addition , photochemistry , stereochemistry , computational chemistry , organic chemistry , molecule
The cover picture shows Two efficient intermolecular oxidative coupling reactions of ( Z )‐enamines with isocyanides via palladium catalysis have been developed. In these transformations, the β‐C(sp 2 )‐H and/or C C bond were cut off selectively by using different anionic ligands, leading to controllable chemodivergent and stereoselective construction of a wide range of ( E )β‐carbamoylenamine derivatives with intramolecular hydrogen bonds. More details are discussed in the article by Jiang et al. on page 712–715.