Competing Crystallization between Lanthanide and Actinide in Acidic Solution Leading to Their Efficient Separation | Zendy

Yin Xuemiao | Zendy; Wang Yaxing | Zendy; Li Xiaoyan | Zendy; Xie Jian | Zendy; Silver Mark A. | Zendy; Chen Lanhua | Zendy; Sheng Daopeng | Zendy; Ji Guoxun | Zendy; Chai Zhifang | Zendy; Wang Shuao | Zendy

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Competing Crystallization between Lanthanide and Actinide in Acidic Solution Leading to Their Efficient Separation

Author(s) -

Yin Xuemiao,

Wang Yaxing,

Li Xiaoyan,

Xie Jian,

Silver Mark A.,

Chen Lanhua,

Sheng Daopeng,

Ji Guoxun,

Chai Zhifang,

Wang Shuao

Publication year - 2019

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.201800468

Subject(s) - chemistry , lanthanide , actinide , europium , crystallization , oxalate , selectivity , inorganic chemistry , americium , nuclear chemistry , organic chemistry , catalysis , ion

Summary of main observation and conclusion We present a new method for generating europium oxalate compounds by decomposing of N ‐methyl 2‐pyrrolidone in HNO 3 media. The reaction exhibits high selectivity towards Eu 3+ over UO 2 2+ , which suggests that these conditions could be applied to a selective crystallization based separation system for trivalent lanthanides and hexavalent actinides.

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