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Cobalt(II)‐Catalyzed Bis‐isocyanides Insertion Reactions with Boric Acids and Sulfonyl Azides via Nitrene Radical Coupling
Author(s) -
Gu ZhengYang,
Zhang Rong,
Wang ShunYi,
Ji ShunJun
Publication year - 2018
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201800307
Subject(s) - chemistry , nitrene , imine , sulfonyl , catalysis , cobalt , combinatorial chemistry , organic chemistry , alkyl
A Co(II)‐catalyzed effective synthesis of amidinium imine derivatives from the reaction of isocyanides and boric acids using organic azides as nitrene source has been developed. This protocol provides a new, environment‐friendly and simple strategy to construct amidinium imine derivatives with a range of substrates without any oxidants and additives.
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