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The Chemistry of Fullerene‐Mixed Peroxides
Author(s) -
Gan Liangbing
Publication year - 2018
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201800298
Subject(s) - chemistry , fullerene , fullerene chemistry , reactivity (psychology) , radical , organic chemistry , photochemistry , polymer chemistry , medicine , alternative medicine , pathology
Peroxy radicals such as Bu t OO · add to fullerenes efficiently to form isomerically pure multiadducts, for example, C 60 (OOBu t ) 6 . The fullerene‐ mixed peroxides exhibit rich chemical reactivity. Further transformation of the peroxy groups has resulted in fullereneols, open‐cage fullerenes, aza‐ and oxafullerenes and/or fulleroids. Practical applications such as photoinitiator remain to be explored for these fullerene‐mixed peroxides.