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Palladium(0)‐Catalyzed Si—Si Bond Insertion by the Terminal Nitrogen of Diazo Compounds
Author(s) -
Liu Zhenxing,
Fu Tianren,
Huo Jingfeng,
Feng Sheng,
Wang Jianbo
Publication year - 2018
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201800292
Subject(s) - chemistry , diazo , palladium , nitrene , nitrogen , catalysis , migratory insertion , polymer chemistry , photochemistry , combinatorial chemistry , organic chemistry
The palladium(0)‐catalyzed nitrogen insertion into cyclic Si—Si bonds has been realized by using N ‐tosylhydrazones/diazo compounds as the nitrogen source. The palladium(II) nitrene formation and subsequent migratory insertion process are proposed as the key steps for this reaction.