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Transition Metal Catalyzed Direct Oxidative Borylation of C—H Bonds
Author(s) -
Jiang ZhongTao,
Wang BiQin,
Shi ZhangJie
Publication year - 2018
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201800223
Subject(s) - borylation , chemistry , catalysis , transition metal , oxidative addition , oxidative phosphorylation , reagent , organoboron compounds , combinatorial chemistry , metal , organic synthesis , organometallic chemistry , medicinal chemistry , photochemistry , organic chemistry , biochemistry , alkyl , aryl
Organoboron is well‐developed and broadly utilized organometallic reagents in organic synthesis due to its extraordinary performances in transition‐metal catalyzed C‐C and C‐X bonds construction. Catalytic C—H borylation and further transformations catalyzed by transition metal catalysts in the absence of oxidants were well studied in decades. However, as known, transition metal catalyzed oxidative C—H borylations were not reviewed up to date. In this article the oxidative borylation of C(sp 2 )‐H and C(sp 3 )‐H bonds were summarized and their mechanisms were also accounted.