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Synthesis of Substituted Naphthalenes by 1,4‐Palladium Migration Involved Annulation with Internal Alkynes
Author(s) -
Wei Dong,
Hu TianJiao,
Feng ChenGuo,
Lin GuoQiang
Publication year - 2018
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201800169
Subject(s) - chemistry , annulation , palladium , aryl , combinatorial chemistry , catalysis , organic chemistry , alkyl
The palladium catalyzed annulation of 1‐bromo‐2‐vinylbenzene derivatives with internal alkynes was realized for the efficient synthesis of substituted naphthalenes. A controllable aryl to vinylic 1,4‐palladium migration process is the key for success.