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Difunctionalization of Alkynes: Synthesis of Novel Fluoropolymer Materials
Author(s) -
Wang Qiang,
Yu Xiwen,
Jin Jiani,
Wu Yang,
Liang Yongmin
Publication year - 2018
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201700630
Subject(s) - fluoropolymer , chemistry , fluorine , catalysis , alkyne , nanotechnology , organic chemistry , materials science , polymer
A Pd‐catalyzed multi‐component carbonylative difluoroalkylation/perfluoroalkylation through the alkyne difunctionalization process has been developed. Besides, new functional fluoropolymer materials have been successfully synthesized. Owing to the presence of the fluorine element, the materials present excellent chemical resistance, high‐temperature‐resistance and outstanding hydrophobicity simultaneously, which may significantly make them great appealing in the industrial production and life science as well.