Premium
Regio‐ and ( E )‐Stereoselective Triborylation of Propargylic Carbonates
Author(s) -
Yang Zheng,
Cao Tao,
Han Yulin,
Lin Weilong,
Liu Qi,
Tang Yang,
Zhai Yizhan,
Jia Minqiang,
Zhang Wanli,
Zhu Tonghao,
Ma Shengming
Publication year - 2017
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201700416
Subject(s) - chemistry , stereoselectivity , selectivity , combinatorial chemistry , regioselectivity , stereochemistry , organic chemistry , catalysis
The triborylation of readily available propargylic carbonates under co‐catalysis of Pd and Cu forming ( E )‐alken‐1,2,3‐triboronates has been developed. The reaction enjoys an excellent regio‐ and E‐ selectivity tolerating a broad scope with many synthetically useful functional groups.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom