Premium
Regio‐ and ( E )‐Stereoselective Triborylation of Propargylic Carbonates
Author(s) -
Yang Zheng,
Cao Tao,
Han Yulin,
Lin Weilong,
Liu Qi,
Tang Yang,
Zhai Yizhan,
Jia Minqiang,
Zhang Wanli,
Zhu Tonghao,
Ma Shengming
Publication year - 2017
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201700416
Subject(s) - chemistry , stereoselectivity , selectivity , combinatorial chemistry , regioselectivity , stereochemistry , organic chemistry , catalysis
The triborylation of readily available propargylic carbonates under co‐catalysis of Pd and Cu forming ( E )‐alken‐1,2,3‐triboronates has been developed. The reaction enjoys an excellent regio‐ and E‐ selectivity tolerating a broad scope with many synthetically useful functional groups.