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Copper‐Catalyzed Direct Oxyphosphorylation of Enamides with P(O)‐H Compounds and Dioxygen
Author(s) -
Liang Wu,
Zhang Zhijie,
Yi Dong,
Fu Qiang,
Chen Suyuan,
Yang Lu,
Du Fengtian,
Ji Jianxin,
Wei Wei
Publication year - 2017
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201700189
Subject(s) - chemistry , catalysis , copper , scope (computer science) , substrate (aquarium) , combinatorial chemistry , organic chemistry , oceanography , computer science , programming language , geology
A simple and convenient copper‐catalyzed direct oxyphosphorylation of enamides with P(O)‐H compounds and dioxygen has been developed under mild conditions. This methodology can allow the synthesis of a series of valuable β ‐ketophosphine oxides/ β ‐ketophosphonates in moderate to good yields with a broad substrate scope simply by using readily‐available starting materials.