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N—H Insertion Reactions Catalyzed by a Dirhodium Metal‐Organic Cage: A Facile and Recyclable Approach for C—N Bond Formation
Author(s) -
Kang Jian,
Chen Lianfen,
Cui Hao,
Zhang Li,
Su ChengYong
Publication year - 2017
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201600818
Subject(s) - chemistry , diazo , cage , catalysis , metal , medicinal chemistry , insertion reaction , rhodium , environmentally friendly , combinatorial chemistry , polymer chemistry , organic chemistry , ecology , mathematics , combinatorics , biology
A heterogeneous metal‐organic cage based on Rh‐Rh bonds [Rh 4 (pbeddb) 4 ( H 2 O ) 2 ( DMAC ) 2 ] ( MOC ‐18; pbeddb 2− = 3,3'‐(1,3‐phenylenebis(ethyne‐2,1‐diyl))dibenzoate) was applied to the N—H insertion reactions with diazo compounds. This method offered an environmentally friendly and highly efficient approach for C—N bond formation.