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Copper Catalyzed Iodosulfenylation of Styrenes by Dual C—H Oxidative Functionalization
Author(s) -
Liu Yurong,
Hu Bolun,
Zhang Xingguo
Publication year - 2017
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201600779
Subject(s) - chemistry , catalysis , surface modification , copper , combinatorial chemistry , dual (grammatical number) , dual role , organic chemistry , polymer chemistry , art , literature
A new method for the synthesis of β ‐iodoalkenyl sulfides via copper catalyzed difunctionalization of styrenes is described. The method allows the formation of two chemical bonds, a C—I bond and a C—S bond, in a single reaction. Using alkenes in place of alkynes to synthesize β ‐iodoalkenyl sulfides is a significant advantage of this methodology for both synthetic and medicinal chemistry.