Premium
Si/C Composites as Negative Electrode for High Energy Lithium Ion Batteries
Author(s) -
Zhang Yi,
Zhu Yusong,
Fu Lijun,
Meng Jixing,
Yu Nengfei,
Wang Jing,
Wu Yuping
Publication year - 2017
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201600663
Subject(s) - lithium (medication) , graphene , electrode , silicon , composite number , fabrication , carbon fibers , electrochemistry , nanotechnology , carbon nanotube , chemistry , ion , composite material , materials science , medicine , alternative medicine , organic chemistry , pathology , endocrinology
Silicon is very promising negative electrode materials for improving the energy density of lithium‐ion batteries ( LIBs ) because of its high specific capacity, moderate potential, environmental friendliness, and low cost. However, the volume variation of Si negative electrodes is huge during lithiation/delithiation processes which results in pulverization, low cycling efficiency, and permanent capacity loss. In order to overcome this problem, tremendous efforts have been attempted. Among them the most successful strategy is to incorporate other components into silicon to form composite, especially the carbon medium. In this mini review, the recent progress on Si/C materials used as negative electrode of LIBs is summarized such as Si/amorphous carbon composite, Si/graphene composites, Si/carbon nanotubes or fibers composites. The fabrication, structure, electrochemical performances of different Si/C composites are discussed. In addition, some future directions are pointed out.