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Synthesis of Substituted Benzoxacycles via a Pd( II )‐Catalyzed Intramolecular Arylation Reaction of Allylic Alcohols
Author(s) -
Li Jingjie,
Tan Ceheng,
Mu Xinpeng,
Gong Jianxian,
Yang Zhen
Publication year - 2017
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201600527
Subject(s) - chemistry , allylic rearrangement , intramolecular force , carbocation , catalysis , annulation , medicinal chemistry , organic chemistry
Herein a Pd‐catalyzed intramolecular allylation reaction of unprotected allylic alcohols was developed, and the reaction proceeded through a Pd( II )‐mediated allylic carbocation species formation, followed by a Friedel‐Crafts type annulation to afford functionalized chromanes.