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Electrosynthesis of Arylsulfonamides from Amines and Sodium Sulfinates Using H 2 O‐NaI as the Electrolyte Solution at Room Temperature
Author(s) -
Zhang Chen,
Chen Yibin,
Yuan Gaoqing
Publication year - 2016
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201600452
Subject(s) - chemistry , electrosynthesis , electrolyte , electrochemistry , sodium , solvent , anode , inorganic chemistry , supporting electrolyte , organic chemistry , electrode
With H 2 O as the solvent and NaI as the supporting electrolyte, a green and efficient electrochemical route has been developed to synthesize arylsulfonamides via I 2 electrogenerated in situ at a graphite anode to promote the reaction of sodium sulfinates with aromatic or aliphatic primary and secondary amines. The target products could be obtained in good to excellent yields at room temperature.