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A Mild and Rapid Synthesis of ( Z )‐ β ‐Sulfonyl Enoates from Sodium Sulfinates and Propargyl Esters
Author(s) -
Jiang Jun,
Zou Huaxu,
Yi Niannian,
Wang Ruijia,
Zhang Hao,
Lan Lixin,
Xiang Jiannan
Publication year - 2016
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201600429
Subject(s) - chemistry , sulfonyl , propargyl , regioselectivity , stereoselectivity , reaction conditions , sodium , organic chemistry , catalysis , alkyl
Abstract Water‐promoted sulfonylation of propargyl esters leading to highly regioselective and stereoselective formation of ( Z )‐ β ‐sulfonyl enoates in excellent yields, by a simple, mild, rapid and environmentally benign reaction procedure is reported.