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Nitration‐Oximization of Styrene Derivatives with tert ‐Butyl Nitrite: Synthesis of α ‐Nitrooximes
Author(s) -
Chumnanvej Napasawan,
Katrun Praewpan,
Pohmakotr Manat,
Reutrakul Vichai,
Soorukram Darunee,
Kuhakarn Chutima
Publication year - 2016
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201600167
Subject(s) - chemistry , nitration , reagent , styrene , nitrite , solvent , organic chemistry , combinatorial chemistry , nitrate , copolymer , polymer
A highly efficient method for direct nitration‐oximization of styrene derivatives using tert ‐butyl nitrite ( t ‐BuONO) in DMSO was developed. The present method offers a convenient and practical approach for the synthesis of α ‐nitrooximes in moderate to high yields. The salient features entail mild reaction conditions, metal‐free reagent, environmentally benign solvent and simple experimental procedure.