Copper‐Catalyzed Redox‐Triggered Remote CH Functionalization: Highly Selective Formation of CCF 3  and CO Bonds | Zendy

Li Taotao | Zendy; Yu Peng | Zendy; Lin JinShun | Zendy; Zhi Yonggang | Zendy; Liu XinYuan | Zendy

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Copper‐Catalyzed Redox‐Triggered Remote CH Functionalization: Highly Selective Formation of CCF 3 and CO Bonds

Author(s) -

Li Taotao,

Yu Peng,

Lin JinShun,

Zhi Yonggang,

Liu XinYuan

Publication year - 2016

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.201500891

Subject(s) - chemistry , surface modification , catalysis , alkyl , redox , nitrogen atom , copper , medicinal chemistry , nitrogen , photochemistry , stereochemistry , organic chemistry

A Cu‐catalyzed remote sp 3 CH/unactivated alkenes functionalization reaction for the concomitant construction of CCF 3 and CO bonds was described. An 1,5‐H radical transfer involving an sp 3 CH bond adjacent to a nitrogen atom and an α ‐CF 3 ‐alkyl radical intermediate derived from unactivated alkenes was observed and demonstrated to proceed via the radical process.

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