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Metal‐Anion Coordination and Linker‐Anion Hydrogen Bonding in the Construction of Metal‐Organic Frameworks from Bipyrazole
Author(s) -
Zhang Erpan,
Jia Qizhang,
Zhang Jun,
Ji Zhenguo
Publication year - 2016
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201500640
Subject(s) - chemistry , linker , metal organic framework , hydrogen bond , metal , ion , coordination complex , inorganic chemistry , molecule , organic chemistry , adsorption , computer science , operating system
Two new two‐dimensional frameworks based on packing of square grids, Cu(Me 4 bpz) 2 (NO 3 ) 2 ( 1 ) and Zn(Me 4 bpz)(SO 4 ) ( 2 ) (Me 4 bpz=3,3′,5,5′‐tetramethyl‐4,4′‐bipyrazole), have been synthesized by mild solvothermal method. In addition to the major metal‐organic linker coordination, they allow us to study how the metal‐inorganic anion coordination and organic linker‐inorganic anion hydrogen bonding affect the resulting structures during the framework assembly.