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Pd‐Catalyzed Synthesis of α ‐Aryl Vinylphosphonates via Suzuki Arylation of α ‐Phosphonovinyl Nonaflates
Author(s) -
Yuan Meijuan,
Fang Yewen,
Zhang Li,
Jin Xiaoping,
Tao Minjia,
Ye Qilin,
Li Ruifeng,
Li Jinjian,
Zheng Hui,
Gu Juejun
Publication year - 2015
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201500414
Subject(s) - chemistry , aryl , catalysis , scope (computer science) , palladium , combinatorial chemistry , organic chemistry , computer science , programming language , alkyl
The first palladium‐catalyzed method for the arylation of α ‐phosphonovinyl nonaflates is described. Using a catalyst comprised of Pd(OAc) 2 and SPhos, terminal and internal α ‐aryl vinylphosphonates could be efficiently accessed under mild conditions. The reaction features a broad coupling partner scope and tolerates many functional groups.