Premium
Ruthenium Trichloride Catalyzed Highly Efficient Deoximation of Oximes to the Carbonyl Compounds and Nitriles without Acceptors
Author(s) -
Liu Yuxiao,
Yang Na,
Chu Changhu,
Liu Renhua
Publication year - 2015
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201500325
Subject(s) - chemistry , catalysis , ruthenium , organic chemistry , rhodium , acceptor , nitrile , combinatorial chemistry , physics , condensed matter physics
An acceptor‐free catalysis protocol for the deoximation of ketoximes and aldoximes using RuCl 3 as the catalyst has been developed. Under the optimized conditions, various oximes were converted to ketones and nitriles with excellent isolated yields.