Bromine Bonding Induced Selective Recognition of Different Guests for Hexaphenylbenzene Bromides in the Solid State | Zendy

Peng Lianhui | Zendy; Zhu Pengcheng | Zendy; Meng Xianggao | Zendy; Zhang Chun | Zendy

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Bromine Bonding Induced Selective Recognition of Different Guests for Hexaphenylbenzene Bromides in the Solid State

Author(s) -

Peng Lianhui,

Zhu Pengcheng,

Meng Xianggao,

Zhang Chun

Publication year - 2015

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.201500293

Subject(s) - chemistry , toluene , supramolecular chemistry , solid state , molecule , bromine , solvent , molecular recognition , polymer chemistry , photochemistry , organic chemistry

With propeller‐like shape, hexaphenylbenzene bromides display different recognition abilities for guest molecules in solid state. HBH can encapsulate CH 2 Cl 2 or Et 2 O molecules selectively from different solvent systems. For DBH , the recognition pattern is dominated between themselves. In CH 2 Cl 2 /toluene/Et 2 O system, toluene molecule can be encapsulated selectively by MBH . In these supramolecular assemblies, bromine bonding plays an important role.

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