Regioselective Oxidation Approaches to Concise Synthesis of (±)‐Canabisin D | Zendy

Li Wenling | Zendy; Liu Qian | Zendy; Liu Hao | Zendy; Chen Peilan | Zendy; Yang Xi | Zendy; Liu Yingying | Zendy

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Regioselective Oxidation Approaches to Concise Synthesis of (±)‐Canabisin D

Author(s) -

Li Wenling,

Liu Qian,

Liu Hao,

Chen Peilan,

Yang Xi,

Liu Yingying

Publication year - 2015

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.201500054

Subject(s) - chemistry , regioselectivity , bromine , yield (engineering) , oxidative coupling of methane , acetone , oxidative phosphorylation , natural product , organic chemistry , medicinal chemistry , combinatorial chemistry , catalysis , biochemistry , materials science , metallurgy

The regioselective effects of tert ‐butyl or bromine as the position‐protecting group of feruloytyamide on the oxidative coupling reactions for the synthesis of natural (±)‐canabisin D were investigated in detail. The coupling yield of 8‐8‐coupled aryldihydronaphthalene product of 5‐Br‐feruloytyamide was higher than that of tert ‐butyl substituted precursor under FeCl 3 ·6H 2 O‐acetone‐water oxidative condition.

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