Synthesis of Pillar[ n ]arene[5− n ]quinines  via  Partial Oxidation of Pillar[5]arene | Zendy

Xie Changdong | Zendy; Hu Weibo | Zendy; Hu Wenjing | Zendy; Liu Yahu A. | Zendy; Huo Jichuan | Zendy; Li Jiusheng | Zendy; Jiang Biao | Zendy; Wen Ke | Zendy

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Synthesis of Pillar[ n ]arene[5− n ]quinines via Partial Oxidation of Pillar[5]arene

Author(s) -

Xie Changdong,

Hu Weibo,

Hu Wenjing,

Liu Yahu A.,

Huo Jichuan,

Li Jiusheng,

Jiang Biao,

Wen Ke

Publication year - 2015

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.201400895

Subject(s) - pillar , chemistry , quinone , reagent , partial oxidation , stereochemistry , medicinal chemistry , organic chemistry , oxygen , structural engineering , engineering

An improved partial oxidation of 1,4‐dimethoxypillar[5]arene (DMP[5]) was described, through which selected pillar[ n ]arene[5− n ]quinones, such as pillar[4]arene[1]quinone, pillar[3]arene[2]quinone, pillar[2]arene[3]quinone and pillar[1]arene[4]quinone, were synthesized by manipulating the ratio of oxidative reagent (NH 4 ) 2 [Ce(NO 3 ) 6 ] to DMP[5].

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