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Synthesis of Pillar[ n ]arene[5− n ]quinines via Partial Oxidation of Pillar[5]arene
Author(s) -
Xie Changdong,
Hu Weibo,
Hu Wenjing,
Liu Yahu A.,
Huo Jichuan,
Li Jiusheng,
Jiang Biao,
Wen Ke
Publication year - 2015
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201400895
Subject(s) - pillar , chemistry , quinone , reagent , partial oxidation , stereochemistry , medicinal chemistry , organic chemistry , oxygen , structural engineering , engineering
An improved partial oxidation of 1,4‐dimethoxypillar[5]arene (DMP[5]) was described, through which selected pillar[ n ]arene[5− n ]quinones, such as pillar[4]arene[1]quinone, pillar[3]arene[2]quinone, pillar[2]arene[3]quinone and pillar[1]arene[4]quinone, were synthesized by manipulating the ratio of oxidative reagent (NH 4 ) 2 [Ce(NO 3 ) 6 ] to DMP[5].