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New Core‐Shell Type Polymeric Supports Based on the Amberlite XAD‐4 Adsorbent: A Novel Synthesis Procedure
Author(s) -
Cyganowski Piotr,
JermakowiczBartkowiak Dorota,
Chęcmanowski Jacek,
Kujawska Małgorzata,
Bryjak Marek
Publication year - 2015
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201400866
Subject(s) - amberlite , chemistry , suspension polymerization , adsorption , divinylbenzene , monomer , polymerization , chemical engineering , copolymer , polymer , porosity , phase (matter) , polymer chemistry , organic chemistry , styrene , engineering
The chloromethyl groups have been introduced into commercial S/DVB copolymer matrixes via interpenetrating polymer networks (IPN) synthesis. The procedure involves impregnation of the Amberlite XAD‐4 adsorbent, with use of the vinylbenzyl chloride (VBC) and divinylbenzene (DVB) monomers mixture, and suspension polymerization process. The syntheses were evaluated by FT‐IR spectra and SEM analyses and furthermore by chlorine content determination as well as characterization of porous structure by nitrogen adsorption at liquid nitrogen temperature. Designed synthesis approach allowed determining organic and water phases composition. Furthermore, impact of an excess of the organic phase removal method has been investigated. Basing on the obtained results it could be stated that the chloromethyl groups, derived from VBC monomer, were successfully introduced into the XAD‐4 structure. Captured SEM images revealed significant changes in the beads' surface morphology after polymerization processes. The presented studies reveal designed and executed synthesis processes, which involve the use of a proper water phase and excess of organic phase removal. Observed changes in the beads' morphology suggest that introduced functionalities are concentrated on the porous surface of the XAD‐4 adsorbent.