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Synthesis and Catalytic Activity of a Grubbs‐Hoveyda Pre‐catalyst Having a Trimeric Resting State
Author(s) -
Liu Guiyan,
Wu Bin,
Wang Jianhui
Publication year - 2015
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201400765
Subject(s) - chemistry , catalysis , olefin metathesis , triazine , salt metathesis reaction , ring closing metathesis , olefin fiber , metathesis , ring (chemistry) , combinatorial chemistry , organic chemistry , polymer chemistry , polymerization , polymer
A Grubbs‐Hoveyda pre‐catalyst having a trimeric resting state based on 2,4,6‐trichloro‐1,3,5‐triazine was synthesized and the complex was characterized by NMR, HRMS and elemental analysis. The activity of this complex for ring‐closing metathesis (RCM) was investigated. The catalytic system possesses high catalytic activity for many different olefin substrates.