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A Novel Self‐Penetrated Framework with New Topology Based on Rigid Ligands
Author(s) -
Lyu Guangxun,
Chen Qihui,
Jiang Feilong,
Zhou Kang,
Su Kongzhao,
Chen Lian,
Yuan Daqiang,
Hong Maochun
Publication year - 2014
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201400425
Subject(s) - chemistry , topology (electrical circuits) , benzene , polymer , crystallography , fluorescence , stereochemistry , organic chemistry , combinatorics , optics , physics , mathematics
A novel coordination polymer, formulated as Zn 6 (TIB) 4 (BPTC) 3 (DMA) 4 (H 2 O) 10 [TIB=1,3,5‐tris(1‐imidazolyl)‐benzene, H 4 BPTC=3,3′,5,5′‐biphenyltetracarboxylate], has been synthesized and structurally characterized. Further investigations reveal that it presents a new topology (topological symbol {6 2 .8 4 }{6 3 }4{6 5 .8}6{6 6 }2) based on self‐penetration, and shows interesting fluorescent properties.