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Co 2 (CO) 8 ‐mediated Selective Reductions of Propargyl Alcohol Derivatives to Alkenes
Author(s) -
Dou Ying,
Xing Ping,
Huang Zuogang,
Jiang Biao
Publication year - 2014
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201400396
Subject(s) - chemistry , alkene , propargyl alcohol , propargyl , yield (engineering) , selectivity , alcohol , medicinal chemistry , organic chemistry , catalysis , materials science , metallurgy
In the presence of Co 2 (CO) 8 and additives, propargyl alcohol derivatives could be reduced to alkenes in moderate to good yield. The selectivity of this reaction could be controlled by adding different additives: with H 2 O as the additive, the major configuration of product is Z‐ alkene; with CF 3 COOH as the additive, the major configuration of product is E ‐alkene.