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A Novel Dimeric BINOL for Enantioselective Recognition of 1,2‐Amino Alcohols
Author(s) -
Velmurugan Krishnaswamy,
Tang Lijun,
Nandhakumar Raju
Publication year - 2014
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201400321
Subject(s) - chemistry , enantioselective synthesis , moiety , hydrogen bond , imine , combinatorial chemistry , stereochemistry , organic chemistry , catalysis , molecule
A novel auxillary chiral dimeric binol has been designed, synthesized, and used to enantioselectively recognize 1,2‐amino alcohols through the three point of interactions, the reversible imine bond, resonance assisted hydrogen bonding and the hydrogen bonding by the additional chiral moiety introduced at the receptor. The enantioselectivities were comparable to those of the previous reported receptors.