Synthesis, Structure and Properties of an Unusual 2D Network Zinc Coordination Polymer Based on Pentanuclear Zinc Cluster | Zendy

Ding Jiangang | Zendy; Yin Chao | Zendy; Li Ke | Zendy; Li Baolong | Zendy; Wu Bing | Zendy

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Synthesis, Structure and Properties of an Unusual 2D Network Zinc Coordination Polymer Based on Pentanuclear Zinc Cluster

Author(s) -

Ding Jiangang,

Yin Chao,

Li Ke,

Li Baolong,

Wu Bing

Publication year - 2014

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.201400263

Subject(s) - chemistry , zinc , thermal stability , cluster (spacecraft) , crystallography , luminescence , coordination polymer , polymer , benzene , stereochemistry , crystal structure , organic chemistry , physics , computer science , programming language , optoelectronics

An unusual zinc(II) coordination polymer [Zn 5 (OH) 2 (bbtz) 2 (bdc) 4 ] n ( 1 ) [bbtz1,4‐bis(1,2,4‐triazol‐1‐ylmethyl)benzene, bdc1,2‐benzenedicarboxylate] was synthesized and characterized. 1 contains an unusual 2D network based on pentanuclear zinc(II) cluster [Zn 5 (OH) 2 ]. Two adjacent pentanuclear Zn(II) clusters are bridged by four bdc ligands and extend to form the one‐dimensional chain. The bbtz ligands further link the one‐dimensional chains, resulting in a two‐dimensional coordination network. The luminescence and thermal stability were investigated.

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