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Synthesis, Structure and Properties of an Unusual 2D Network Zinc Coordination Polymer Based on Pentanuclear Zinc Cluster
Author(s) -
Ding Jiangang,
Yin Chao,
Li Ke,
Li Baolong,
Wu Bing
Publication year - 2014
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201400263
Subject(s) - chemistry , zinc , thermal stability , cluster (spacecraft) , crystallography , luminescence , coordination polymer , polymer , benzene , stereochemistry , crystal structure , organic chemistry , physics , computer science , programming language , optoelectronics
An unusual zinc(II) coordination polymer [Zn 5 (OH) 2 (bbtz) 2 (bdc) 4 ] n ( 1 ) [bbtz1,4‐bis(1,2,4‐triazol‐1‐ylmethyl)benzene, bdc1,2‐benzenedicarboxylate] was synthesized and characterized. 1 contains an unusual 2D network based on pentanuclear zinc(II) cluster [Zn 5 (OH) 2 ]. Two adjacent pentanuclear Zn(II) clusters are bridged by four bdc ligands and extend to form the one‐dimensional chain. The bbtz ligands further link the one‐dimensional chains, resulting in a two‐dimensional coordination network. The luminescence and thermal stability were investigated.