Premium
A 1,2,3,4‐Tetrahydrofullerene Derivative Generated from a [60]Fulleroindoline: Regioselective Electrosynthesis and Computational Study
Author(s) -
Xiao Yang,
Wang Guanwu
Publication year - 2014
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201400205
Subject(s) - regioselectivity , electrosynthesis , chemistry , derivative (finance) , fullerene , electrochemistry , surface modification , computational chemistry , combinatorial chemistry , organic chemistry , catalysis , electrode , financial economics , economics
A 1,2,3,4‐tetrahydro[60]fullerene with a five‐membered heterocycle fused to a [5,6] junction was obtained with high regioselectivity by electrochemical functionalization of a [60]fulleroindoline. The structure was determined by spectroscopic data. A plausible reaction mechanism supported by computational calculations is proposed.