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Special Chiral C 2 ‐Symmetric endo‐ Biarylnorbornane: Synthesis and Structure Illustration
Author(s) -
Cai Chonglin,
Chen Ruigang,
He Jun,
Feng Juntao,
Zhang Xing
Publication year - 2014
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201400162
Subject(s) - chemistry , stereoselectivity , stereochemistry , combinatorial chemistry , crystallography , organic chemistry , catalysis
A highly efficient and practical synthesis for strained special scaffold of chiral endo ‐biarylnorbornane starting from available norbornadione was achieved with direct stereoselective dehydroxylation of tertiary alcohol as the key step, and the structure was illustrated by X‐ray structural analysis.