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Self‐Assembly of Chiral Nano‐bowl from Chiral Pd‐complex Building Corners and 4,7‐Phenanthroline Linkers
Author(s) -
Yu Lina,
Jiang Xuanfeng,
Yu Shuyan
Publication year - 2015
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201400085
Subject(s) - chemistry , phenanthroline , palladium , self assembly , crystallography , ligand (biochemistry) , stereochemistry , elemental analysis , organic chemistry , catalysis , receptor , biochemistry
A chiral [M 3 L 3 ] 6+ ‐type nanobowl reported here was self‐assembled from cis ‐protected mono‐palladium complex [(RRdiph)Pd](NO 3 ) 2 (where RRdiph= (1 R ,2 R )‐(+)‐1,2‐diphenylethylenediamine) as chiral corners and 4,7‐phenanthroline ligand ( L ) as linkers in aqueous media. The hydrophobic cavity‐containing metallo‐macrocycle [Pd 3 L 3 ] 6+ ·6NO 3 ( 1 ) with a syn, syn, syn orientation has been characterized by 1 H NMR spectroscopy, elemental analysis, CD spectra and X‐ray diffraction determination.