Premium
Efficient CS Cross‐Coupling of Thiols with Aryl Iodides Catalyzed by Cu(OAc) 2 ·H 2 O and 2,2′‐Biimidazole
Author(s) -
Zong Chenglong,
Liu Jianli,
Chen Shengyan,
Zeng Runsheng,
Zou Jianping
Publication year - 2014
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201300830
Subject(s) - chemistry , aryl , catalysis , alkyl , medicinal chemistry , coupling reaction , organic chemistry , polymer chemistry
The classical Ullmann CS cross coupling reaction of aryl iodides with aromatic/alkyl thiols under catalysis of 15 mol% Cu(OAc) 2 ·H 2 O and 15 mol% 2,2′‐biimidazole works at 80°C in DMSO for 3 h to provide a variety of aryl sulfides in good to excellent yields.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom