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Palladacycle‐Catalyzed Carbonylation of Aryl Iodides or Bromides with Aryl Formates
Author(s) -
Chen Guangwei,
Leng Yuting,
Yang Fan,
Wang Shiwei,
Wu Yangjie
Publication year - 2013
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.201300675
Subject(s) - chemistry , aryl , carbonylation , catalysis , carbon monoxide , organic chemistry , alkyl
An efficient palladacycle‐catalyzed aromatic carbonylation reaction of aryl formates with aryl iodides or bromides has been developed. Commercially available and easily prepared aryl formates were employed as carbonyl sources without the use of external carbon monoxide. The present catalytic system shows broad functional group tolerance and affords aryl benzoate derivatives in good to excellent yields.