TEMPO‐Mediated Oxidation of Primary Alcohols to Aldehydes under Visible Light and Air | Zendy

Liu Dongwang | Zendy; Zhou Hongxia | Zendy; Gu Xiangyong | Zendy; Shen Xiaoqin | Zendy; Li Pixu | Zendy

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TEMPO‐Mediated Oxidation of Primary Alcohols to Aldehydes under Visible Light and Air

Author(s) -

Liu Dongwang,

Zhou Hongxia,

Gu Xiangyong,

Shen Xiaoqin,

Li Pixu

Publication year - 2014

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.201300541

Subject(s) - chemistry , primary (astronomy) , visible spectrum , homogeneous , photochemistry , molecular oxygen , alcohol oxidation , redox , oxygen , organic chemistry , alcohol , optoelectronics , physics , astronomy , thermodynamics

A homogeneous visible light photoredox TEMPO‐mediated selective oxidation of primary alcohols to the corresponding carbonyl compounds was developed using molecular oxygen from air as the terminal oxidant. Ru(bpy) 3 (PF 6 ) 2 (bpy: bipyridyl) and Ir(dtb‐bpy)(ppy) 2 (PF 6 ) (dtb‐bpy: 4,4′‐di‐ tert ‐butyl‐2,2′‐bipyridyl; ppy: 2‐phenylpyridine) were used as the sensitizers.

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